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101.
Emilio San-Fabián José Pérez-Jordá Federico Moscardó 《Theoretical chemistry accounts》1990,77(3):207-212
Summary The correlation energy of two- and four-isoelectronic series, a representative example for which the existing spin-density functionals fails, is calculated using the Colle and Salvetti method, considering mono- and multideterminantal wave functions. The results are in agreement with experimental data, and show the potentiality of this method when it is applied to wave functions including the most relevant configurational features. Also, results for the ionization energies and electron affinities of first- and second-row atoms are reported. 相似文献
102.
103.
介绍了对尿汞快速测定法的改进,用消泡剂磷三丁酸消除尿中泡沫,并讨论了尿汞测定的最佳条件,本法的相对标准偏差为4.8-9.0%,回收率94-101%。 相似文献
104.
Marti E. Kaisersberger E. Emmerich W.-D. 《Journal of Thermal Analysis and Calorimetry》2004,77(3):905-934
The definitions of the temperature resolution, the so-called resolution of DSC instruments given in literature are discussed.
A new definition of the resolution for DSC instruments is presented and outlined. The main characteristic introduced in this
new definition is a minimum between two caloric events as a prerequisite of an existing resolution. Possible candidates of
test substances have been evaluated. The oligomer n-hexatriacontane is revealing an interesting phenomenon, namely a lambda
transition which is in the peak temperature only 2 K lower than the melting temperature of 76°C. The substance was selected
as an ideal test substance for the quantification of the resolution of DSC instruments. The lambda transition is a second
order process which may reach under certain conditions the saturation of the occurring molecular dislocation within 0.2 K,
and after saturation the heat flow rate drops sharply down. Investigations concerning the main characteristics of n-hexatriacontane
in respect to the temperatures of transition (lambda transition and melting), to the involved enthalpies, and to the resolution
factors were performed as functions of the sample mass and the heating rate. The importance of relevant evaluation procedures
increasing the resolution factors of DSC curves are discussed and these procedures are integrated into the testing of the
resolution. The necessity for widening the experimental scope from instruments to evaluation procedures is forced by the existence
of instruments with built-in signal treatments based on electronic devices and software procedures. A comparison with literature
data is outlined for all of the mentioned characteristic values of n-hexatriacontane.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
105.
In this paper, calculating the molecular internal rotating steric factor of polymers by the radiation crosslinking method is studied and a relationship between the molecular internal rotating steric factor (σ) and crosslinking parameter βis established~([1]) by taking account of the effect of polymer chain flexibility on βvalue, σvalue of polymer obtained by this method is in agreement with that given with other method. 相似文献
106.
神经生长因子的化学发光标记与检测 总被引:1,自引:0,他引:1
以辣根过氧化物酶(HRP)和吖啶酯(AE)为化学发光标记试剂分别标记神经生长因子(NGF)单克隆抗体,经分离纯化制成标记抗体(HRP-Ab,AE-Ab),采用化学发光免疫分析法(CLIA)对NGF进行检测,其检出限为0.5ng/mL,线性范围为2~128ng/mL.10例样本分别用CLIA和RIA进行检测,其结果无显著性差异. 相似文献
107.
为研究四川省重点河段水环境的安全性,利用综合评价指数法和模糊综合评价决策的数学模型对主要水系干流和支流河段的水质安全性做出了评价.结果显示,岷江流域的水质安全性较差,主要的污染物为重金属汞和铁,沱江和涪江流域的水质安全性较好. 相似文献
108.
J. Díaz-Ferrero M.C. Rodríguez-Larena L. Comellas B. Jiménez 《Trends in analytical chemistry : TRAC》1997,16(10):1865-573
The usual methods for determining polychlorinated dibenzo-p-dioxins (PCDD), polychlorinated dibenzofurans (PCDF) and polychlorinated biphenyls (PCB) are generally expensive and time consuming. This fact has favored the development of faster and cheaper techniques, based on immunoassays and bioassays. This paper reviews these bioanalytical methods and their analytical importance at the present moment. 相似文献
109.
Impact Responses of Prismatic Lithium-Ion Battery Based on the Membrane Factor Method北大核心CSCD 下载免费PDF全文
Aimed at the internal short circuit problem due to large deformation of the prismatic lithium-ion battery cell under impact loadings, a simplified battery model was first established. Then the motion equations of velocity and displacement based on the membrane factor method were proposed. With the effects of the face-sheet thickness and the densification region on the normalized final deflection, impact response characteristics of prismatic battery cells were investigated in detail. The results show that, the improved motion equations involving the membrane factor can reflect the dynamic response mechanisms of the prismatic battery cell under impact loadings, and the large deflection under high-speed impact can be predicted. With the increase of the face-sheet thickness, the deflection of the battery cell’s lower part decreases obviously. However, the densification region expands with the face-sheet thickness. The deflection and the densification region of the cell’s lower part both increase with the inner core density of the battery. This proposed impact model provides a theoretical guidance for the multi-functional integrated dynamic design of prismatic battery cells. © 2022 Editorial Office of Applied Mathematics and Mechanics. All rights reserved. 相似文献
110.
现有药品质量安全监管的相关研究多从理性假设出发探讨政府与企业的互动机理,鲜有考虑企业质量安全意识的有限理性,导致模型对现实的解释能力不足。运用前景理论,通过价值函数和权重函数构建演化博弈的收益前景矩阵,研究了政府和药品生产企业的博弈过程,得到了影响企业质量安全意识的约束条件及因素。同时,研究了上市许可持有人质量激励、惩罚机制对药品生产企业质量安全意识的影响。研究结果表明:过度自信、风险偏好等是影响企业质量安全意识的重要因素;上市许可持有人的质量激励与惩罚能否发挥作用取决于企业的风险态度;在质量激励、惩罚条件下,上市许可持有人需加大监督或惩罚力度来改善企业的质量安全意识。 相似文献